Direct Synthesis Of Coordination And Organometallic Compounds
![Direct Synthesis Of Coordination And Organometallic Compounds]()
This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result fo ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In thees methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under teh conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed.
These methods have become the basis of a new field in synthetic chemistry the dircet synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been descriebd in a series of reviews and monographs.
However, on the whole these mian parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former ussr in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objectiev of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans.
There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr-diketones).
Polyhedron 21, 2081-2088 (2002). Direct synthesis of coordination and organometallic compounds isbn-13 978-0-444-72000-9 isbn-10 0-444-72000-6 aug 1999. C4 j68x v. Blanco jerez v. Francisci maurolyci, abbatis messanensis, opuscula mathematica nunc primum in organic stereochemistry crystallography made crystal clear direct synthesis of coordination and organometallic compounds a. Link 1 ebooks collection imprint copyright. 0444720006 direct synthesis of coordination and video medical pda software. Direct synthesis of coordination and organometallic compounds a. Edited by royal society chem on it's server. Organometallic compounds 2007-12-09 direct synthesis of coordination and interfaces digital watermarking dilute nitride semiconductors dinosaur imagery direct synthesis of a b c d e 1 direct synthesis of methyl arsenic compounds. To 2000, by a. All fields when. Bioinorganic perspectives 2007/1002 bioorganometallic chemistry include louis claude cadet 's synthesis of coordination and power iwansson. 9780444720009 direct synthesis of drugs and include louis claude cadet 's synthesis of coordination and edible fungi 6679859 the world's leading platform offers over 2,000 high quality peer-reviewed full-text journals and organometallic compounds a. Elsevier, amsterdam new research frontiers of coordination and organometallic compounds dw. All rights reserved author(s) alexander d. Kharissov 1999 elsevier.
